Molecular Spectroscopy and Group Theory

(CHEM 543-2007)—Tim Keiderling

Department of Chemistry

University of Illinois at Chicago

 

Spring 2007, 132 SES (probably will not move?), 2-4 PM Tu-Th

Extra session: if needed??? (note—extended lectures cover missed classes and problem solving)

 

Professor: Tim Keiderling

Office: 5407 B SES, Tele:  6-3156  --  Best to contact by e-mail: tak@uic.edu

 

Grader – Boyang Wang,  

Prefered Contact: e-mail: <bwang9@uic.edu>  Office: 4244 SES

 

To understand the interests of the lecturer better, visit - Keiderling group web site link:  http://www.chem.uic.edu/takgroup/

 

Warning--this course site is mostly an information transfer mechanism.

It is useful for problem sets and old exams, and thus is always under construction!!

--returning to it for periodic review, rather than printing, is suggested


Syllabus

Suggested book list

Outline of topics

Computer Project Exercise (uncertain at present)

Homework : Set #1, Set #2, Set #3, Set #4, Set #5, Set #6, Set #7, Set #8, Set #9, Set #10

Solutions: Set #1, Set #2, Set #3, Set #4, Set #5, Set#6, Set#7, Set#8, Set#9

 

Old Exams – sample questions:  Hour Exam #1, Hour Exam # 2, Final Exam

This years Exams: Midterm1—light and matter, Midterm 2—Group theory

         Exam Solutions:  Exam1, Exam2

 

Links to other Molecular Spectroscopy Sites

 

QM and Spectroscopy Notes

REVIEW ! Notes from previous course material (i.e. should have been part of Chem 542):

Atomic Energy Levels and spectra (term symbols)

Diatomics - Born-Oppenheimer and rotation vibration separation

Diatomics – molecular orbital approximations

Old review notes (techniques, etc.) from other courses:

         Angular Momentum

         Matrices

         Approximation Methods

         Slater Determinants

 

Extra Notes specific to Chem 543—this course

         Wave Equations from Maxwell Equations

         Group Theory Examples

                          Second Set Examples (GOT and Characters)

 

Lecture notes for Spring 2007:

Periodically I will make revised pdf versions of my notes available. These will be edited from previous course offerings and hopefully will be available in a timely basis, depending on how typing progresses.

1: Introduction, and review of Chem 542

2: Interaction of Light and Matter: -(revise Thurs notes and unedited Tues notes)

3. Selection Rules, Atoms and Diatomics, rotation and rotation - vibration

4. Group Theory,

5. Vibrational Spectra

6. Electronic Spectra  

 

 

Below are links to old handwritten notes you may find useful from previous course:

0: Introduction,

1: Interaction of Light and Matter:

2. Selection Rules, Atoms and Diatomics, rotation and rotation - vibration

3. Group Theory Part 1, Part 2, Part 3, Part 4, Part 5,

4. Vibrational Spectra

5. Electronic Spectra   Part 1, Part 2, Part 3, Part 4, Part 5

 

Something borrowed: One minute (OK maybe 15!) guide to quantum chemistry